|本期目录/Table of Contents|

[1]李雪雨,宋万诚,温彦威,等.弹性体隔热材料技术研究进展[J].合成橡胶工业,2021,6:512-518.
　LI Xue-yu,SONG Wan-cheng,WEN Yan-wei,et al.Technical research progress in elastomeric heat shielding materials[J].China synthetic rubber industy,2021,6:512-518.
点击复制

弹性体隔热材料技术研究进展(PDF)

《合成橡胶工业》[ISSN:1000-1255/CN:62-1036/TQ]

期数:
2021年6期
页码:
512-518
栏目:
出版日期:
2021-11-10

文章信息/Info

Title:
Technical research progress in elastomeric heat shielding materials
文章编号:
1000-1255（2021）06-0512-07
作者:
李雪雨1; 宋万诚1; 温彦威2; 贾红兵1
1.南京理工大学 软化学和功能材料教育部重点实验室，南京 210094； 2.上海航天化工应用研究所，浙江 湖州 313000
Author(s):
LI Xue-yu1;  SONG Wan-cheng1;  WEN Yan-wei2;  JIA Hong-bing1
（1.Key Laboratory for Soft Chemistry and Functional Materials of Ministry of Education, Nanjing University of Science and Technology, Nanjing 210094, China; 2.Shanghai Institute of Aerospace Power Technology, Huzhou 313000, China）
关键词:
弹性体隔热材料; 聚合物烧蚀材料; 固体火箭发动机; 耐烧蚀性能; 综述
Keywords:
elastomeric heat shielding materials;  polymer ablative materials;  solid rocket motor;  ablative property;  review
分类号:
TQ 336.9
DOI:
10.19908/j.cnki.ISSN1000-1255.2021.06.0512
文献标识码:
A
摘要:
概述了弹性体隔热材料的烧蚀机理，并从弹性体基体和填充体系两方面系统总结了弹性体隔热材料的结构组成，同时综述了近年来国内外弹性体隔热材料在阻燃改性和树脂改性等方面的研究进展，最后对其在热防护系统中的应用前景进行了展望。
Abstract:
Ablation mechanism of elastomeric heat shielding materials (EHSMs) was briefly introduced and structural composition of EHSMs was systematically summarized from the viewpoint of elastomer matrix and filler system.Moreover, the research progress of flame retardant modification and resin modification of EHSMs at home and abroad was reviewed with 58 references.Finally, application prospects of EHSMs in the field of thermal protection system was prospected.

参考文献/References

[1] Rallini M，Puri I，Torre L，et al.Effect of liquid resol on the mechanical and thermal properties of EPDM/Kynol elastomeric heat shielding materials[J].Polymer Engineering and Science，2017，57（6）：513-520.
[2] Natali M，Kenny J M，Torre L.Science and technology of polymeric ablative materials for thermal protection systems and propulsion devices：A review[J].Progress in Materials Science，2016，84：192-275.
[3] Dugast G，Settar A，Chetehouna K，et al.Experimental and numerical analysis on the thermal degradation of reinforced si-licone-based composites：Effect of carbon fibres and silicon carbide powder contents[J].Thermochimica Acta，2020，686：178563.
[4] Natali M，Rallini M，Kenny J，et al.Effect of wollastonite on the ablation resistance of EPDM based elastomeric heat shiel-ding materials for solid rocket motors[J].Polymer Degradation and Stability，2016，130：47-57.
[5]George K，Panda B P，Mohanty S，et al.Recent developments in elastomeric heat shielding materials for solid rocket motor casing application for future perspective[J].Polymers for Advanced Technologies，2018，29（1）：8-21.
[6] Li Jiang，Xi Kun，Lv Xiang，et al.Characteristics and formation mechanism of compact/porous structures in char layers of EPDM insulation materials[J].Carbon，2018，127：498-509.
[7] Kumar L M，Usha K M，Anandapadmanabhan E N，et al.Effect of fibre orientation on the properties and functional performance of ablative materials for solid rocket motor[J].Transactions of the Indian Institute of Metals，2017，70（9）：2407-2413.
[8] 裴高林，丁方政，赖亮庆，等.丁腈橡胶和丁腈酯橡胶性能对比[J].合成橡胶工业，2020，43（3）：246-249.
[9] Zhou Ruitao，Zheng Hongbing，Zheng Yuansuo.Study of the aligned pyrolysis gas channels in fiber-reinforced ablative materials[J].Polymer Degradation and Stability，2015，119：9-13.
[10] Arabgol F，Kokabi M，Bahramian A R.Ablation behavior of organoclay-NBR insulator：Modeling and experimental[J].Fire and Materials，2018，42（7）：859-872.
[11] Iqbal N，Sagar S，Khan M B，et al.Aluminum silicate fibers impregnated acrylonitrile butadiene rubber composites：Ablation，thermal transport/stability，and mechanical inspection[J].Journal of Applied Polymer Science，2013，130（6）：4392-4400.
[12] 孙黎，毕忠华，高梅等.氢化丁腈橡胶的研究进展[J].特种橡胶制品，2020，41（1）：60-64.
[13] Guan Yue，Zhang Lingxin，Zhang Liqun，et al.Study on ablative properties and mechanisms of hydrogenated nitrile buta-diene rubber （HNBR） composites containing different fillers[J].Polymer Degradation and Stability，2011，96（5）：808-817.
[14] 吴文明，焦保雷，甄恩龙，等.添加剂对硅橡胶耐高温性的影响[J].有机硅材料，2019，33（1）：13-18.
[15] Hanu L G，Simon G P，Mansouri J，et al.Development of polymer-ceramic composites for improved fire resistance[J].Journal of Materials Processing Technology，2004，153/154（1）：401-407.
[16] Hanu L G，Simon G P，Cheng Y B.Preferential orientation of muscovite in ceramifiable silicone composites[J].Materials Science and Engineering （A）：Structural Materials：Properties，Microstructure and Processing，2005，398（1/2）：180-187.
[17] Sanden R.Castable silicone based heat insulations for jet engines[J].Polymer Testing，2002，21（1）：61-64.
[18] Yang Dong，Zhang Wei，Jiang Benzheng.Ceramization and oxidation behaviors of silicone rubber ablative composite under oxyacetylene flame[J].Ceramics International，2013，39（2）：1575-1581.
[19] Zhang Yang，He Jiyu，Yang Rongjie.The effects of phosphorus-based flame retardants and octaphenyl polyhedral oligome-ric silsesquioxane on the ablative and flame-retardation properties of room temperature vulcanized silicone rubber insulating composites[J].Polymer Degradation and Stability，2016，125：140-147.
[20] Yang Dong，Zhang Wei，Jiang Benzheng，et al.Silicone rubber ablative composites improved with zirconium carbide or zirconia[J].Composites （Part A）：Applied Science and Manufacturing，2013，44：70-77.
[21] Kim J T，Lee D Y，Oh T S，et al.Characteristics of nitrile-butadiene rubber layered silicate nanocomposites with silane coupling agent[J].Journal of Applied Polymer Science，2003，89（10）：2633-2640.
[22] Natali M，Rallini M，Puglia D，et al.An armadillo-like flexible thermal protection system for inflatable decelerators：A novel paradigm[J].Macromolecular Materials and Engineering，2014，299（3）：379-390.
[23] Bhuvaneswari C M，Sureshkumar M S，Kakade S D，et al.Ethylene-propylene diene rubber as a futuristic elastomer for insulation of solid rocket motors[J].Defence Science Journal，2006，56（3）：309-320.
[24] Natali M，Rallini M，Puri I，et al.Thermal and ablation resistance of syntactic foamed EPDM-based heat shielding materials[C]∥Damore A，Acierno D，Grassia L.9th International Conference on Times of Polymers and Composites：From Aerospace to Nanotechnology.Ischia：American Institute of Physics，2018：020043.
[25] Ma Xiaofeng，Li Jianhua，Wu Jian，et al.Effects of phenolic short fibers on properties of EPDM insulations[J].China Plastics Industry，2019，47（7）：31-34.
[26] Zhang Shuangkun，Zhang Peng，Ali S，et al.Effects of PAN-based carbon fibers and its precursors on ethylenepropylene-diene monomer insulations：Morphology and properties[J].Polymer Composites，2018，39（9）：3336-3340.
[27] He J，Zhang X，Li X，et al.Effect of OMMT on ablative，thermal and flame retardant properties of ethylene propylene diene rubber （EPDM） composite[J].Plastics Rubber and Compo-sites，2015，44（5）：206-210.
[28] Zhou Ruitao，Zheng Yuansuo，Sun Lili，et al.Study on pro-perties of boron phenolic resin/butadiene acrylonitrile rubber （NBR） ablative materials[J].Journal of Solid Rocket Techno-logy，2007，30（2）：159-162.
[29] Levchik S V，Weil E D.Thermal decomposition，combustion and fire-retardancy of polyurethanes—A review of the recent literature[J].Polymer International，2004，53（11）：1585-1610.
[30] Allcorn E K，Natali M，Koo J H.Ablation performance and characterization of thermoplastic polyurethane elastomer nanocomposites[J].Composites （Part A）：Applied Science and Manufacturing，2013，45：109-118.
[31] 魏健，于向伟，孙浩等.影响热塑性聚氨酯弹性体性能的因素[J].弹性体，2019，29（5）：29-32.
[32] Jing Qifei，Law J Y，Tan L P，et al.Preparation，characterization and properties of polycaprolactone diol-functionalized multi-walled carbon nanotube/thermoplastic polyurethane compo-site[J].Composites （Part A）：Applied Science and Manufacturing，2015，70：8-15.
[33] Jiao Chuanmei，Zhao Xiaolong，Song Wenkui，et al.Synergistic flame retardant and smoke suppression effects of ferrous powder with ammonium polyphosphate in thermoplastic polyurethane composites[J].Journal of Thermal Analysis and Calorimetry，2015，120（2）：1173-1181.
[34] Bassyouni M，Iqbal N，Iqbal S S，et al.Ablation and thermo-mechanical investigation of short carbon fiber impregnated elastomeric ablatives for ultrahigh temperature applications[J].Polymer Degradation and Stability，2014，110：195-202.
[35] Jaramillo M，Koo J H，Natali M.Compressive char strength of thermoplastic polyurethane elastomer nanocomposites[J].Polymers for Advanced Technologies，2014，25（7）：742-751.
[36] Yu Lin，Zhou Shengtai，Zou Huawei，et al.Thermal stability and ablation properties study of aluminum silicate ceramic fiber and acicular wollastonite filled silicone rubber composite[J].Journal of Applied Polymer Science，2014，131（1）：39700
[37] Liu Yanhui，Su Jingyu，Yin Zhengshuai，et al.Ablation and mechanical investigation of heat vulcanizing silicone rubber （HVSR） composite containing carbon fibers[J].Journal of Polymer Engineering，2017，37（5）：521-528.
[38] Jia Xiaolong，Li Guang，Sui Gang，et al.Effects of pretreated polysulfonamide pulp on the ablation behavior of EPDM composites[J].Materials Chemistry and Physics，2008，112（3）：823-830.
[39] Han Zhongqiang，Qi Shengli，Liu Wei，et al.Surface-modified polyimide fiber-filled ethylenepropylenediene monomer insulations for a solid rocket motor：Processing，morphology，and properties[J].Industrial & Engineering Chemistry Research，2013，52（3）：1284-1290.
[40] Bourbigot S，Flambard X.Heat resistance and flammability of high performance fibres：A review [J].Fire and Materials，2002，26（4/5）：155-168.
[41] Ahmed A F，Hoa S V.Thermal insulation by heat resistant polymers for solid rocket motor insulation[J].Journal of Composite Materials，2012，46（13）：1549-1559.
[42] George K，Panda B P，Biswal M，et al.Ethylene propylene diene monomer rubber-based heat shielding materials for solid rocket motor：Impact of Kevlar fiber reinforcement on the thermal and mechanical properties[J].Polymers for Advanced Technologies，2020，31（6）：1280-1290.
[43] Li Jiang，Liu Kai，Guo Mengfei，et al.Ablation and erosion characteristics of EPDM composites under SRM operating conditions[J].Composites （Part A）：Applied Science and Manufacturing，2018，109：392-401.
[44] Li P，Duan H Y，Liu Y F，et al.Multi-walled carbon nanotubes as secondary fibre fillers for property improvement of short carbon fibre-reinforced silicone rubber[J].Bulletin of Materials Science，2019，42（4）：177.
[45] Song Jiuqiang，Huang Zhixiong，Qin Yan，et al.Effects of zirconium silicide on the vulcanization，mechanical and ablation resistance properties of ceramifiable silicone rubber composites[J].Polymers，2020，12（2）：15.
[46] Zhang Guangwu，Wang Fuzhong，Huang Zhixiong，et al.Improved ablation resistance of silicone rubber composites by introducing montmorillonite and silicon carbide whisker[J].Materials，2016，9（9）：723.
[47] 李志颖，刘锋，杨新飞.阻燃剂及补强填料对三元乙丙橡胶烧蚀性能的影响[J].特种橡胶制品，2020，41（1）：24-27.
[48] Farajpour T，Bayat Y，Abdollahi M，et al.Effect of borax on the thermal and mechanical properties of ethylene-propylene-diene terpolymer rubber-based heat insulator[J].Journal of Applied Polymer Science，2015，132（19）：41936.
[49] Chen Xilei，Ma Cuiyong，Jiao Chuanmei.Synergistic effects between iron-graphene and ammonium polyphosphate in flame-retardant thermoplastic polyurethane[J].Journal of Thermal Analysis and Calorimetry，2016，126（2）：633-642.
[50] Hao Huijuan，Zhou Xuyuan，Shen Zhaohong，et al.Study on the ablative properties of ethylene propylene diene terpolymer/silsesquioxane insulation materials[J].Journal of Applied Polymer Science，2020，137（6）：48365.
[51] Rallini M，Puri I，Torre L，et al.Boron based fillers as char enhancers of EPDM based heat shielding materials for SRMs：A comparative analysis[J].Composite Structures，2018，198：73-83.
[52] Rallini M，Torre L，Kenny J M，et al.Effect of boron carbide nanoparticles on the thermal stability of carbon/phenolic composites[J].Polymer Composites，2017，38（9）：1819-1827.
[53] Rashid N，Naghmana R，Zulfiqar A，et al.7Effects on thermal and ablative properties of phenolic resin （novolac） blended acrylonitrile butadiene rubber[J].Fibers and Polymers，2018，19（6）：1318-1326.
[54] Mu Qiuhong，Peng Dan，Ju Wei，et al.Synthesis and effects of MDT silicone resin on PMPS-based ablative composites[J].Journal of Applied Polymer Science，2015，132（9）：41571.
[55] Comer A J，Ray D，Clancy G，et al.Hydrothermal in-plane-shear strength of carbon fibre/benzoxazine laminates manufactured out-of-autoclave by liquid-resin-infusion[J].Composite Structures，2019，213：261-270.
[56] Chen L，Ren D X，Chen S J，et al.Copolymerization of phthalonitrile-based resin containing benzoxazine and cyanate ester：Curing behaviors，fiber-reinforced composite laminates and improved properties[J].Express Polymer Letters，2019，13（5）：456-468.
[57] Gao Jinglong，Li Zhixuan，Li Jiayi，et al.Ablation behavior of silicone rubber-benzoxazine-based composites for ultra-high temperature applications[J].Polymers，2019，11（11）：1844.
[58] Wu S，Zhang S，Akram R，et al.EPDM-based heat-shielding materials modified by hybrid elastomers of silicone or polyphosphazene[J].High Performance Polymers，2019，31（9/10）：1112-1121.

备注/Memo

备注/Memo:
收稿日期：2020-08-15；修订日期：2021-07-02。
作者简介：李雪雨（1996—），女，安徽淮北人，硕士研究生。主要从事高分子材料改性的研究工作。
基金项目：中国航空科学基金资助项目（2016 ZF 59009）。
更新日期/Last Update: 2021-11-10