|本期目录/Table of Contents|

[1]祁极冰,王科峰,杨 通,等.聚合物脱挥强化设备与技术研究进展[J].合成橡胶工业,2024,3:275-282.
 QI Ji-bing,WANG Ke-feng,YANG Tong,et al.Research progress in equipment and technology of intendifying polymer devolatilization[J].China synthetic rubber industy,2024,3:275-282.
点击复制

聚合物脱挥强化设备与技术研究进展(PDF)

《合成橡胶工业》[ISSN:1000-1255/CN:62-1036/TQ]

期数:
2024年3期
页码:
275-282
栏目:
出版日期:
2024-05-15

文章信息/Info

Title:
Research progress in equipment and technology of intendifying polymer devolatilization
文章编号:
1000-1255(2024)03-0275-08
作者:
祁极冰12王科峰3杨 通3刘有智2?鄢
(1. 太原学院 材料与化学工程系,太原 030032; 2. 中北大学 化工过程强化山西省重点实验室,太原 030051; 3. 中国石油石油化工研究院 合成树脂研究所,北京 102206)
Author(s):
QI Ji-bing12 WANG Ke-feng3 YANG Tong3 LIU You-zhi2
( 1. Institute of Materials and Chemical Engineering, Taiyuan University, Taiyuan 030032, China; 2. Shanxi Province Key Laboratory of Chemical Process Intensification, North University of China, Taiyuan 030051, China; 3. Synthetic Resin Research Division, Petrochemical Research Institute, PetroChina, Beijing 102206, China)
关键词:
聚合物脱挥挥发分过程强化机理高黏度旋转填料床综述
Keywords:
polymer devolatilization volatile process intensification mechanism high viscosity rotating packed bed review
分类号:
TQ 315
DOI:
DOI:10.19908/j.cnki.ISSN1000-1255.2024.03.0275
文献标识码:
A
摘要:
简述了聚合物脱挥的传递机理和过程特征,阐述了脱挥传质机理及过程强化,从脱挥工艺和脱挥设备方面综述了聚合物脱挥过程强化的方法,指出了新型的脱挥设备与工艺是实现聚合物高效脱挥的关键,并着重阐述了超临界流体、超声空化、超重力等聚合物脱挥新技术的研究现状和发展趋势。
Abstract:
The transfer mechanism and process characteristics of polymer devolatilization were briefly described, and the mechanism and process intensification of devolatilization mass transfer were introduced. The methods of polymer devolatilization process intensification were summarized from the devolatilization equipment and devolatilization process, and it was pointed out that the new devolatilization equipment and process were the key to realize the high-efficiency devolatilization of polymer. The research status and development trend of new technologies of polymer devolatilization, such as supercritical fluid, ultrasonic cavitation and high gravity were emphatically expounded with 62 refe-rences.

参考文献/References

[1] 刘有智. 超重力分离工程[M]. 北京:化学工业出版社, 2020:71-74.[2] 奚桢浩, 仇枭逸, 赵玲. 聚合物高效脱挥技术进展[J]. 化工进展, 2019, 38(1): 80-90.[3] Bai Zhenhui, Liu Yun, Su Tingting, et al. Effect of hydroxyl monomers on the enzymatic degradation of poly(ethylene succinate), poly(butylene succinate), and poly(hexylene succinate)[J]. Polymers, 2018, 10(1): 90.[4] 中华人民共和国国家卫生和计划生育委员会. GB 4806. 6—2016食品安全国家标准 食品接触用塑料树脂 [S]. 北京: 中国标准出版社, 2017:1-18.[5] 张华, 温亮, 闫国春. 高黏聚合物系脱挥设备研究进展[J]. 化工设备与管道, 2022, 59(3): 42-47.[6] 奚桢浩. 流场结构化的新型高粘缩聚反应器[D]. 上海: 华东理工大学, 2010.[7] 谢建军, 潘勤敏, 潘祖仁. 聚合物系脱挥研究进展[J]. 合成橡胶工业, 1998, 21(3): 135-141.[8] 邓立伟. 聚甲醛生产中的挥发分脱除[J]. 合成树脂及塑料, 2017, 34(1): 52-56.[9] Majoni S, Chaparadza A. Thermal degradation kinetic study of polystyrene/organophosphate composite[J]. Thermochimica Acta, 2018, 662 (10): 8-15.[10] 成文凯, 王嘉骏, 顾雪萍, 等. 聚合物搅拌脱挥设备及其CFD模拟研究进展[J]. 化工进展, 2016, 35(5): 1283-1288.[11] 于志家. 泡点露点与闪蒸计算[J]. 化工高等教育, 2013, 30(2): 84-87.[12] 李大伟. 聚合物脱挥技术及应用[J]. 合成纤维工业, 2022, 45(4): 58-63.[13] Han Chang Dae, Yoo Hee Ju. Studies on structural foam processing(IV):Bubble growth during mold filling[J]. Polymer Engineering and Science, 1981, 21(9): 518-533.[14] Foster R W, Lindt J T. Bubble growth controlled devolatilization in twin-screw extruders[J]. Polymer Engineering and Science, 1989, 29(3): 178-185.[15] Niyogi D, Kumar R, Gandhi K S. Modeling of bubble-size distribution in water and freon co-blown free rise polyurethane foams[J]. Journal of Applied Polymer Science, 2014, 131(18): 9098-9110.[16] Biesenberger J A, Sebastian D H. Principles of polymerization engineering[M]. New York: John Wiley & Sons, 1983: 673.[17] 谢建军. 聚合物系起泡脱挥基础研究[D]. 杭州: 浙江大学, 1997.[18] Hu Yangxu, Liu Zhiping, Yuan Xigang, et al. Molecular mechanism for liquid-liquid extraction: Two-film theory revi-sited[J]. AIChE Journal, 2017, 63(6): 2464-2470.[19] Li Woyuan, Wu Wei, Zou Haikui, et al. A mass transfer model for devolatilization of highly viscous media in rotating packed bed[J]. Chinese Journal of Chemical Engineering, 2010, 18(2): 194-201.[20] Li Woyuan, Wu Wei, Zou Haikui, et al. Process intensification of VOC removal from high viscous media by rotating packed bed[J]. Chinese Journal of Chemical Engineering, 2009, 17(3): 389-393.[21] 付豪. 高粘卧式脱挥反应器实验研究和数值模拟[D]. 北京: 北京化工大学, 2020.[22] 刘振河. 错流旋转填料床特性与聚合物脱挥应用研究[D]. 太原: 中北大学, 2007.[23] 张霞. 超重力脱除挥发分的工艺研究[D]. 北京: 北京化工大学, 2020.[24] Albalak R J. 聚合物脱挥[M]. 赵旭涛, 龚光碧, 谷育生, 等译. 北京: 化学工业出版社, 2005:1-5.[25] Werner H. Devolatilization of polymers in multi-screw devolatilizers[J]. Kunststoffe-German Plastics,1981,71(1):18-26.[26] 顾培韵. 聚合物系的脱挥发分设备[J]. 合成橡胶工业,1994,17(4): 195-199.[27] 王佳宁. 高速脱挥反应器的研究[D]. 北京: 北京化工大学, 2015.[28] 冯连芳, 曹松峰, 顾雪萍, 等. 高粘搅拌聚合反应装置[J]. 合成橡胶工业, 2001, 24(5): 257-261.[29] 赵思维. 粘性流体落管式降膜脱挥特性的实验与CFD模拟研究[D]. 杭州: 浙江大学, 2017.[30] 夏燕敏, 陈德铨. 落条式脱挥器在本体聚合中的应用[J]. 石油化工, 2000, 29(11): 879-883.[31] 李沃源, 毋伟, 邹海魁, 等. 超重力旋转填充床用于高黏聚合物脱挥的研究进展[J]. 化工进展, 2010, 29(2): 211-216, 232.[32] 都佩华. 一种降膜式薄膜蒸发器: CN, 208611814 U[P]. 2019-03-19.[33] 吴利东, 沈军良, 魏东, 等. 降膜式薄膜蒸发器: CN, 101804261 B[P]. 2011-09-07.[34] Parrillo D, Singh P. Method for isolating polyphenylene ether polymer resins from solution: US, 6860966[P]. 2005-03-01.[35] Secor R M. A mass transfer model for a twin-screw extruder[J]. Polymer Engineering and Science, 1986, 26(9): 647-652.[36] Albalak R J, Tadmor Z, Talmon Y. Polymer melt devolatilization mechanisms[J]. AIChE Journal, 1990, 36(9): 1313-1320.[37] 李杨. 双螺杆反应挤出法开环聚合制备聚乳酸的研究[D]. 上海: 东华大学, 2014.[38] Cheng Wengkai, Wang Jiajun, Gu Xueping, et al. Film formation in a horizontal twin-shaft rotating disk reactor for polymer devolatilization[J]. Chemical Engineering Science, 2017, 166: 19-27.[39] Hirschfeld S, Hermann L, Wünsch O. Polymer devolatilization in a rotating apparatus[J]. Proceedings in Applied Mathematics and Mechanics, 2015, 15(1): 511-512.[40] 潘勤敏, 蒋春跃, 潘祖仁. 聚苯乙烯的超临界流体脱挥[J]. 高分子材料科学与工程, 2000, 16(3): 135-137.[41] 蒋春跃, 程榕, 高建荣, 等. 超临界流体增强聚酯薄膜中的质量传递[J]. 化工学报, 2005, 56(7): 1187-1191.[42] Yilg■r I, McGrath J E. Novel supercritical fluid techniques for polymer fraction and purification[J]. Polymer Bulletin, 1984, 12: 499-506.[43] Alsoy S, Duda J L. Supercritical devolatilization of polymers[J]. AIChE Journal, 1998, 44(3): 582-590.[44] 魏丹毅, 蒋春跃. 聚苯乙烯超临界流体脱挥研究[J]. 化学工程, 1999, 27(3): 5-7,16,1.[45] 蒋春跃, 高建荣, 陈杰, 等. 一种聚苯乙烯的超临界流体脱挥方法: CN, 101220109 A[P]. 2008-07-16.[46] C·弗里德斯多夫, P·布兰特, G·基斯. 用于超临界聚合方法的相分离器和单体再循环: CN, 101563374 A[P]. 2009-10-21. [47] Cristancho D E, Guzman J D, Taylor C, et al. Supercritical extraction of volatile organic components from polyethylene pellets[J]. The Journal of Supercritical Fluids, 2012, 69: 124-130.[48] Daneshvar M, Kamali H, Masoomi M, et al. Supercritical carbon dioxide grafting of glycidyl methacrylate onto medium density polyethylene and purification of residual monomer and initiator[J]. The Journal of Supercritical Fluids, 2012, 70: 119-125.[49] 周茹英. 超声波强化聚乙烯脱挥研究[D]. 杭州: 浙江大学, 2004.[50] Xie Tingting, Wu Hong, Bao Wenting, et al. Enhanced compatibility of PA 6/POE blends by POE-g-MAH prepared through ultrasound-assisted extrusion[J]. Journal of Applied Polymer Science, 2010, 118(3): 1846-1852.[51] Tang Siye, Wang Ye, Liu Dazhuang, et al. Novel approach to the ultrasonic degradation of polymers: Development of a general kinetic equation[J]. Progress in Reaction Kinetics and Mechanism, 2013, 38(4): 397-407.[52] 刘有智. 超重力化工过程与技术[M]. 北京: 国防工业出版社, 2009: 9-15.[53] 陈建峰. 超重力技术及应用:新一代反应与分离技术[M]. 北京: 化学工业出版社, 2002: 1-10.[54] Jimkuo H. Mass transfer of centrifugally enhanced polymer devolatilization by using foam metal packed bed[D]. Cleveland: Case Western Reserve University, 1995.[55] 丹·特托威德约约, 小乔治·J·夸德德, 克拉克·J·克明斯, 等. 聚合物脱挥发分的离心方法和设备: CN, 99807157.9[P]. 2001-07-25. [56] 杨胜, 林佳璋, 曾益民, 等. 利用旋转填充床从高粘度液体中移除其中所含的挥发成分的方法: CN, 1454917 A[P]. 2003-11-12.[57] 刘会雪. 超重力法脱除脲醛树脂中游离甲醛基础及应用研究[D]. 太原: 中北大学, 2008.[58] 陈建峰, 李沃源, 初广文, 等. 一种脱除聚合物挥发分的方法及装置: CN, 101372522 [P]. 2009-09-25.[59] Li Yanbin, Liu Wei, Zhang Xia, et al. Enhancement of devolatilization performance in a rotating packed bed with diffe-rent packing structures[J]. Separation and Purification Technology, 2021, 278: 119527.[60] 卢俊晶. 高粘体系中易挥发组分扩散系数与亨利系数的研究[D]. 北京: 北京化工大学, 2017.[61] 黄翔. 高速分散反应器传质性能的实验研究[D]. 北京: 北京化工大学, 2016.[62] Ma Shugang, Bao Yuyun, Gao Zhengming, et al. Experimental studies and modeling of devolatilization of highly viscous solution in high-speed disperser[J]. Journal of Chemical Enginee-ring of Japan, 2017, 50(4): 236-243.

备注/Memo

备注/Memo:
聚烯烃弹性体技术开发科研项目(2020 B-2619);太原学院青年科研项目(23 TYQN 23)。
更新日期/Last Update: 1900-01-01