[1]张小萍,Isayevich Avraam Isayev,丛后罗,等.超声波振幅对轮胎胶粉超声脱硫工艺及性能的影响[J].合成橡胶工业,2022,3:201-206.
ZHANG Xiao-ping,Isayevich Avraam ISAYEV,CONG Hou-luo,et al.Effect of ultrasonic amplitude on ultrasonic desulfurization process and performance of ground tire rubber[J].China synthetic rubber industy,2022,3:201-206.
点击复制
超声波振幅对轮胎胶粉超声脱硫工艺及性能的影响(PDF)
《合成橡胶工业》[ISSN:1000-1255/CN:62-1036/TQ]
- 期数:
-
2022年3期
- 页码:
-
201-206
- 栏目:
-
- 出版日期:
-
2022-05-15
文章信息/Info
- Title:
-
Effect of ultrasonic amplitude on ultrasonic desulfurization process and performance of ground tire rubber
- 文章编号:
-
1000-1255(2022)03-0201-06
- 作者:
-
张小萍; Isayevich Avraam Isayev; 丛后罗; 王艳秋; 张延阁
-
(1. 徐州工业职业技术学院 材料工程学院,江苏 徐州 221140;2. 美国阿克伦大学 聚合物工程系,俄亥俄州 阿克伦 44325-0301)
- Author(s):
-
ZHANG Xiao-ping; Isayevich Avraam ISAYEV; CONG Hou-luo; WANG Yan-qiu; ZHANG Yan-ge
-
(1. Materials Engineering College, Xuzhou College of Industrial Technology, Xuzhou 221140, China;2. Department of Polymer Engineering, The University of Akron, Akron, OH 44325-0301, USA)
-
- 关键词:
-
超声波振幅; 轮胎胶粉; 超声脱硫工艺; 流变性能; 硫化特性; 力学性能
- Keywords:
-
ultrasonic amplitude; ground tire rubber; ultrasonic desulfurization process; rheological property; curing characteristics; mechanical property
- 分类号:
-
TQ 330.56
- DOI:
-
DOI:10.19908/j.cnki.ISSN1000-1255.2022.03.0201
- 文献标识码:
-
B
- 摘要:
-
以40目废旧轮胎胶粉为原料,采用超声脱硫工艺,使用超声同向旋转双螺杆挤出机制备了脱硫废旧轮胎胶粉(DGTR),研究了超声波振幅对脱硫工艺过程中口型压力和功率消耗,DGTR的外观形貌、流变性能和硫化特性,以及DGTR硫化胶力学性能的影响。结果表明,随着超声波振幅的增加,DGTR的凝胶含量、黏度及储能模量逐渐降低,损耗因子逐渐增大;当超声波振幅为13 μm时,超声DGTR中交联键断裂数量最多,由此表明此时DGTR的脱硫程度最高。此外,随着超声波振幅的增加,DGTR硫化胶的拉伸强度逐渐降低,扯断伸长率逐渐增加。
- Abstract:
-
The desulfurized ground tire rubber (DGTR) was prepared from 40 mesh waste ground tire rubber by ultrasonic desulfurization process in an ultrasonic co-rotating twin- screw extruder. The effects of ultrasonic amplitude on the die pressure and power consumption during ultrasonic desulfurization process, the external morphology, rheological properties and curing characteristics of DGTR, and the mechanical properties of the re- vulcanized DGTR were studied. The results showed that with the increase in ultrasonic amplitude, the gel content, viscosity and storage modulus of the DGTR decreased gradually and loss factor increased gradually. When the ultrasonic amplitude was set as 13 μm, the number of the broken cross-linked bonds of DGTR was the largest during ultrasonic desulfurization process, which meant that the desulfurization degree of DGTR was the highest. Moreover, the tensile strength of the re-vulcanized DGTR decreased gradually and elongation at break increased gradually with the increasing ultrasonic amplitude.
参考文献/References
[1] Isayev A I, Chen J, Tukachinsky A. Novel ultrasonic technology for devulcanization of waste rubbers[J]. Rubber Chemistry and Technology, 1995, 68(2): 267-280.[2] Tukachinsky A, Schworm D, Isayev A I. Devulcanization of waste tire rubber by powerful ultrasound[J]. Rubber Chemistry and Technology, 1996, 69(1): 92-103.[3] Isayev A I, Yushanov S P, Kim Seok-Ho, et al. Ultrasonic devulcanization of waste rubbers: Experimentation and modeling[J]. Rheologica Acta, 1996, 35(6): 616-630.[4] Isayev A I, Yushanov S P, Chen J. Ultrasonic devulcanization of rubber vulcanizates(I): Process model[J]. Journal of Applied Polymer Science, 1996, 59(5): 803-813.[5] Feng Wenglai, Isayev A I. High-power ultrasonic treatment of butyl rubber gum: Structure and properties[J]. Journal of Polymer Science (Part B): Polymer Physics, 2005, 43(3): 334-344.[6] 翟俊学, 张萍, 赵树高. 硫化橡胶微波脱硫机理的再讨论[J]. 特种橡胶制品,2004, 25(6): 35-40.[7] 赵素合, 覃柳莎, 王雅琴, 等. 一种废旧橡胶的生物脱硫方法: 中国, 200710098537.6[P]. 2008-10-22.[8] 赵素合, 覃柳莎, 姜广明, 等. 微生物脱硫胶粉/天然橡胶共混胶的性能[J].合成橡胶工业, 2008, 31(3): 209-213.[9] Kojima M, Ogawa K, Mizoshima H, et al. Devulcanization of sulfur-cured isoprene rubber in supercritical carbon dioxide[J]. Rubber Chemistry and Technology, 2003, 76(4): 957-968.[10] 江宽, 史金炜, 赵为, 等. 利用超临界二氧化碳流体脱硫再生丁基橡胶[J]. 合成橡胶工业, 2012, 35(1): 64-69.[11] 张立群, 葛佑勇, 王士军, 等. 一种采用双螺杆挤出机脱硫再生硫化橡胶的方法: 中国, 200910080211.X[P]. 2009-08-19.[12] 王睿, 缪国兵, 吴盾, 等. 用双螺杆挤出机脱硫制备再生胶的工艺及性能[J]. 合成橡胶工业, 2010, 33(4): 313-316.[13] Feng Wenglai, Isayev A I, Meerwall E. Molecular mobility in ultrasonically treated butyl gum and devulcanized butyl rubber[J]. Polymer, 2004, 45(25): 8459-8467.[14] Feng Wenglai, Isayev A I. Blends of ultrasonically devulcanized tire-curing bladder and butyl rubber[J]. Journal of Mate-rials Science, 2005, 40(11): 2883-2889.[15] Isayev A I, Liang Tian, Lewis T M. Effect of particle size on ultrasonic devulcanization of tire rubber in twin-screw extruder[J]. Rubber Chemistry and Technology, 2014, 87(1): 86-102.
备注/Memo
- 备注/Memo:
-
江苏省高校优秀中青年教师境外研修项目;2020年江苏省青蓝工程项目。
更新日期/Last Update:
2022-05-15