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作者:: 严志轩^a; b; 张孝娟^a; b; 刘莉^a; 孙翀^b; 刘吉文^b; 孙立水^a; 刘福胜^c; 何丽霞^a; c; 青岛科技大学 a. 高性能聚合物及成型技术教育部工程研究中心； b. 高分子科学与工程学院； c. 化工学院，山东青岛 266042

Author(s):: YAN Zhi-xuan^a; b; ZHANG Xiao-juan^a; b; LIU Li^a; SUN Chong^b; LIU Ji-wen^b; SUN Li-shui^a; LIU Fu-sheng^c; HE Li-xia^a; c; a.Engineering Research Center for High Performance Polymer and Molding Technoolgy of Ministry of Education; b.School of Polymer Science and Engineering; c.School of Chemical Engineering, Qingdao University of Science and Technology, Qingdao 266042, China

Keywords:: polyisoprene; synthesis; microstructure; modified; click chemistry; epoxidation; review

摘要:: 总结了各类微观结构不同的聚异戊二烯的制备方法，归纳了在聚异戊二烯主链上引入特殊基团的改性手段。通过调控催化剂的种类、结构调节剂、温度等因素可以制得微观结构不同的聚异戊二烯，采用羟基化、环氧化及偶联等改性手段大大拓宽了聚异戊二烯材料的应用现状和发展前景。

Abstract:: The preparation methods of polyisoprene with different microstructure and the modification methods of introducing special groups into the main chain of polyisoprene were summarized with 46 references. Polyisoprene with different microstructure could be prepared by adjusting the type of catalyst, structure regulator and temperature. The application status and development prospect of polyisoprene materials were greatly widened by means of hydroxylation, epoxidation and coupling.